Referierte Publikationen

The serrodyne principle enables an electromagnetic signal to be frequency shifted by applying a linear phase ramp in the time domain. This phenomenon has been exploited to frequency shift signals in the radiofrequency, microwave and optical regions of the electromagnetic spectrum over ranges of up to a few gigahertz, for example, to analyse the Doppler shift of radiofrequency signals for noise suppression and frequency stabilization. Here we employ this principle to shift the centre frequency of high-power femtosecond laser pulses over a range of several terahertz with the help of a nonlinear multi-pass cell. We demonstrate our method experimentally by shifting the central wavelength of a state-of-the-art 75 W frequency comb laser from 1,030 nm to 1,060 nm and to 1,000 nm. Furthermore, we experimentally show that this wavelength-shifting technique supports coherence characteristics at the few hertz-level while improving the temporal pulse quality. The technique is generally applicable to wide parameter ranges and different laser systems, enabling efficient wavelength conversion of high-power lasers to spectral regions beyond the gain bandwidth of available laser platforms.

Table-top extreme ultraviolet (EUV) microscopy offers unique opportunities for label-free investigation of biological samples. Here, we demonstrate ptychographic EUV imaging of two dried, unstained model specimens: germlings of a fungus (Aspergillus nidulans), and bacteria (Escherichia coli) cells at 13.5 nm wavelength. We find that the EUV spectral region, which to date has not received much attention for biological imaging, offers sufficient penetration depths for the identification of intracellular features. By implementing a position-correlated ptychography approach, we demonstrate a millimeter-squared field of view enabled by infrared illumination combined with sub-60 nm spatial resolution achieved with EUV illumination on selected regions of interest. The strong element contrast at 13.5 nm wavelength enables the identification of the nanoscale material composition inside the specimens. Our work will advance and facilitate EUV imaging applications and enable further possibilities in life science.

With metallic-magnetic calorimeters (MMCs), promising detectors for high-precision X-ray spectrometry in atomic and fundamental physics experiments are available. In this work, we present a pilot experiment based on a maXs-30 type MMC-spectrometer for recording X-rays emitted in collisions of lithium-like uranium ions with a molecular nitrogen gas jet in the internal target of the ESR storage ring of the GSI. Sample spectra have been measured, and a multitude of X-ray transitions have been unambiguously identified. As a first test and for comparison with data recorded at an EBIT, the 2s Lamb shift in lithium-like uranium was estimated.

A new scheme of ion acceleration by crossing two ultraintense laser pulses in a near-critical relativistically transparent plasma is proposed. One laser, acting as a trigger, preaccelerates background ions in its radial direction via the laser-driven shock. Another crossed laser drives a comoving snowplow field which traps some of the preaccelerated ions and then efficiently accelerates them to high energies up to a few giga-electron-volts. The final output ion beam is collimated and quasimonoenergetic due to a momentum-selection mechanism. Particle-in-cell simulations and theoretical analysis show that the scheme is feasible and robust.

We study the collision of two optical laser pulses in a pump-probe setup using beams with circular and elliptic cross section and estimate the number of discernible signal photons induced by quantum vacuum nonlinearities. In this analysis we study strategies to optimize the quantum vacuum signal discernible from the background of the driving lasers. One of the main results is that the collision of two maximally focused lasers does not lead to the best discernible signal. Instead, widening the focus typically improves the signal to background separation in the far field. For petawatt class lasers, an optimal choice of the focus waist yields several discernible photons per shot in contrast to no discernible signal for tight focusing. Further enhancement is possible by using an elliptical waist.

Following the work of Giulio Racah and others from the 1940s onward, the rotational symmetry of atoms and ions, e.g., the conservation of angular momentum, has been utilized in order to efficiently predict atomic behavior, from their level structure to the interaction with external fields, and up to the angular distribution and polarization of either emitted or scattered photons and electrons, while this rotational symmetry becomes apparent first of all in the block-diagonal structure of the Hamiltonian matrix, it also suggests a straight and consequent use of symmetry-adapted interaction amplitudes in expressing the observables of most atomic properties and processes. We here emphasize and discuss how atomic structure theory benefits from exploiting this symmetry, especially if open-shell atoms and ions in different charge states need to be combined with electrons in the continuum. By making use of symmetry-adapted amplitudes, a large number of excitation, ionization, recombination or even cascade processes can be formulated rather independently of the atomic shell structure and in a language close to the formal theory. The consequent use of these amplitudes in existing codes such as Grasp will therefore qualify them to deal with the recently emerging demands for developing general-purpose tools for atomic computations.

We combine a recent construction of a Becchi-Rouet-Stora-Tyutin (BRST)-invariant, nonlinear massive gauge fixing with the background field formalism. The resulting generating functional preserves background -field invariance as well as BRST invariance of the quantum field manifestly. The construction features BRST-invariant mass parameters for the quantum gauge and ghost fields. The formalism employs a background Nakanishi-Lautrup field which is part of the nonlinear gauge-fixing sector and thus should not affect observables. We verify this expectation by computing the one-loop effective action and the beta function of the gauge coupling as an example. The corresponding Schwinger functional generating connected correlation functions acquires additional one-particle reducible terms that vanish on shell. We also study off-shell one -loop contributions in order to explore the consequences of a nonlinear gauge fixing scheme involving a background Nakanishi-Lautrup field. As an application, we show that our formalism straightforwardly accommodates nonperturbative information about propagators in the Landau gauge in the form of the so-called decoupling solution. Using this nonperturbative input, we find evidence for the formation of a gluon condensate for sufficiently large coupling, whose scale is set by the BRST-invariant gluon mass parameter.

We present a theoretical investigation of the elastic Rayleigh scattering of X-rays by atomic targets. Special attention is paid to the question of how the polarization of the scattered photons is affected if the incident light is itself polarized. In particular, we found that the circular polarization of the incoming X-rays may lead to a remarkable modification of the linear polarization of the scattered photons. Based on this \textasciigrave circular-to-linear-polarization-transfer\textquotesingle and on the fact that the linear polarization of X-rays can be conveniently observed by solid-state Compton detectors, we argue that Rayleigh scattering may be used as a tool for circular polarimetry of hard X-rays. To illustrate our proposal, we performed detailed calculations of 145 and 500 keV circularly polarized photons scattered by lead atoms. Based on these calculations, we found that the photon scattering under large angles with respect to the incident beam direction is most favorable for the circular polarimetry of hard X-rays. In particular, for 500 keV photon energy and scattering angles around 70 deg we found a remarkable modification of the linear polarization of scattered light for the case when the incident radiation is circularly polarized.

We probe the energy-loss enhancement in preequilibration and the charge-equilibration time for highly charged Xe ions (qin = 15-26) at near-Bohr velocity impinging on an Al target by measuring the dependence of the Xe L-shell x-ray yield on the initial charge state of the ions. The present results are found to be very consistent with those obtained in ion-transmission thin-foil experiments. The charge-equilibrium time is measured in the near-Bohr velocity region of highly charged ions in solids. Moreover, for the present collision system it is demonstrated by measuring the inner-shell x rays that the ionization of the inner-shell electrons of the projectile ions starts to contribute to ion energy loss at near-Bohr velocity.

The low-energy heavy ion storage ring CRYRING was transported from Stockholm to Darmstadt, modernized and reconfigured, and recommissioned as CRYRING@ESR. The machine is now in operation with all installations in service and is available as a user facility for experiments proposed through the SPARC collaboration. During the 2020-2022 period, we brought a number of experimental installations into service and used them to measure first data: the ultra-cold electron cooler for merged-beam electron-ion collisions, the gas jet target for atomic collisions, a next-generation microcalorimeter-based X-ray spectroscopy setup, and others. Ions can be injected either in low charge states from a local ion source through a 300 keV/u RFQ linac, or in high charge states from the GSI accelerator chain through ESR. This allows for very broad access to ions across the entire periodic table. CRYRING@ESR is able to de- or accelerate ions and cool and store beams of isotopically pure species in a desired charge state. While the analysis is still largely ongoing, the first experimental data already show that the machine reached its expected performance level, and our high expectations regarding achievable resolution in spectroscopy experiments have been fulfilled. With access to new classes of ions available through ESR injection and a new generation of experimental instrumentation, CRYRING@ESR is a unique facility for experiments with heavy, highly charged ions. Here, we will review our present setup and machine performance, discuss the data from our first commissioning experiments and briefly preview the upcoming new installations for the coming years.

Spontaneous parametric down-conversion (SPDC) is a widely used source for photonic entanglement. Years of focused research have led to a solid understanding of the process, but a cohesive analytical description of the paraxial biphoton state has yet to be achieved. We derive a general expression for the spatio-temporal biphoton state that applies universally across common experimental settings and correctly describes the nonseparability of spatial and spectral modes. We formulate a criterion on how to decrease the coupling of the spatial from the spectral degree of freedom by taking into account the Gouy phase of interacting beams. This work provides new insights into the role of the Gouy phase in SPDC, and also into the preparation of engineered entangled states for multidimensional quantum information processing.

This article studies the impact of mechanical deformations on the performance of a coaxial-type cryogenic current comparator (CCC). Such deformations may become a concern as the size of the CCC increases (e.g., when used as a diagnostic device in a particle accelerator facility involving beamlines with a large diameter). In addition to static deformations, this article also discusses the effect of mechanical vibrations on the CCC performance.

Spontaneous parametric down-conversion (SPDC) is widely used in quantum applications based on photonic entanglement. The efficiency of photon pair generation is often characterized by means of a sinc(L delta k/2) function, where L is the length of the nonlinear medium and delta k is the phase mismatch between the pump and down-converted fields. In theoretical investigations, the sinc behavior of the phase mismatch has often been approximated by a Gaussian function exp (-alpha x(2)) in order to derive analytical expressions for the SPDC process. Different values have been chosen in the literature for the optimization factor alpha, for instance, by comparing the widths of sinc and Gaussian functions or the momentum of down-converted photons. As a consequence, different values of alpha provide different theoretical predictions for the same setup. Therefore an informed and unique choice of this parameter is necessary. In this paper, we present a choice of alpha which maximizes the validity of the Gaussian approximation. Moreover, we also discuss the so-called super-Gaussian and cosine-Gaussian approximations as practical alternatives with improved predictive power for experiments.

The design and performances of a newly built electrostatic charge state analyzer constructed to act as a spectrometer for keV/u ions are reported. It consists of two 90 & LCIRC; curved electrodes enclosed by Matsuda electrodes. This setup was recently tested using Ar9+ and Ar12+ ion beams at an energy of 10 keV per charge unit. This spectrometer achieves a good separation of different charge states formed by electron capture processes during collisions between primary ions and the residual gas. Thanks to these first tests, we have identified up to three different background contributions on the detector that need to be reduced or suppressed.

A Raman-based label-free analytical method was developed to detect the antibiotic ciprofloxacin (CIP) in various pharmaceutical formulations in the presence of different matrices (e.g., ear drops, eye drops and infusion solutions). The Raman spectral analysis is performed for semiquantification in the case of a low background Raman signal, i.e., the signal originating from the excipient and carrier substance of the formulation does not interfere with the fingerprint spectrum of ciprofloxacin. In the case of a background spectrum rich in Raman modes originating from the excipient and carrier substance of the formulation, the pharmaceutical formulation is diluted 1:5000, and thus, the background signal is undetectable. Due to the high affinity of ciprofloxacin towards metallic surfaces, surface-enhanced Raman spectroscopy (SERS) is applied to allow for the sensitive detection of ciprofloxacin. Moreover, the developed measurement routine can be applied to monitor the degradation of the active component ciprofloxacin within the pharmaceutical formulation. The developed assay can therefore be extended to the pharmaceutical industry for quality control in assay applications or the preparation of individualized medicines.

Metastable states of ions can be sufficiently populated in absorbing and emitting astrophysical media, enabling spectroscopic plasma-density diagnostics. Long-lived states appear in many isoelectronic sequences with an even number of electrons, and can be fed at large rates by various photonic and electronic mechanisms. Here, we experimentally investigate beryllium-like and carbon-like ions of neon and iron that have been predicted to exhibit detectable features in astrophysical soft X-ray absorption spectra. An ion population generated and excited by electron impact is subjected to highly monochromatic X-rays from a synchrotron beamline, allowing us to identify K alpha transitions from metastable states. We compare their energies and natural line widths with state-of-the-art theory and benchmark level population calculations at electron densities of 10(10.5) cm(-3).

In this article, we report on the latest investigations and achievements in proton beam shaping with our laser-driven ion beamline at GSI Helmholtzzentrum fiir Schwerionenforschung GmbH. This beamline was realized within the framework of the Laser Ion Generation, Handling, and Transport (LIGHT) collaboration to study the combination of laser-driven ion beams with conventional accelerator components. At its current state, the ions are accelerated by the high-power laser PHELIX via target normal sheath acceleration, and two pulsed high-magnetic solenoids are used for energy selection, transport, and transverse focusing. In between the two solenoids, there is a rf cavity that gives the LIGHT beamline the capability to longitudinally manipulate and temporally compress ion bunches to sub-nanosecond durations. To get optimal results, the rf cavity has to be synchronized with the PHELIX laser and therefore a reliable measurement of the temporal ion beam profile is necessary. In the past, these measurements showed unexpected correlations between the temporal beam profile and the phase as well as the electric field strength of the cavity. In this article, we present a numerical simulation of the beam transport through the LIGHT beamline which explains this behavior by a beam filamentation. We also report on our latest experimental campaigns, in which we combined transverse and longitudinal focusing for the first time. This led to proton bunches with a peak intensity of (3.28 +/- 0.24) x 10(8) protons/ (ns mm(2)) at a central energy of (7.72 +/- 0.14) MeV. The intensity refers to a circle with a diameter of (1.38 +/- 0.02) mm that encloses 50% of the protons in the focal spot at the end of the beamline. The temporal bunch width at this position was (742 +/- 40) ps (FWHM).

In the present contribution, we use x-rays to monitor charge-induced chemical dynamics in the photoionized amino acid glycine with femtosecond time resolution. The outgoing photoelectron leaves behind the cation in a coherent superposition of quantum mechanical eigenstates. Delayed x-ray pulses track the induced coherence through resonant x-ray absorption that induces Auger decay. Temporal modulation of the Auger electron signal correlated with specific ions is observed, which is governed by the initial electronic coherence and subsequent vibronic coupling to nuclear degrees of freedom. In the time-resolved x-ray absorption measurement, we monitor the time-frequency spectra of the resulting many-body quantum wave packets for a period of 175 fs along different reaction coordinates. Our experiment proves that by measuring specific fragments associated with the glycine dication as a function of the pump-probe delay, one can selectively probe electronic coherences at early times associated with a few distinguishable components of the broad electronic wave packet created initially by the pump pulse in the cation. The corresponding coherent superpositions formed by subsets of electronic eigenstates and evolving along parallel dynamical pathways show different phases and time periods in the range of (-0.3 +/- 0.1 ) pi <= phi <= ( 0.1 +/- 0.2 ) pi and 18.2(-1.4)(+1.7) <= T <= 23.9(-1.1)(+1.2 )fs. Furthermore, for long delays, the data allow us to pinpoint the driving vibrational modes of chemical dynamics mediating charge-induced bond cleavage along different reaction coordinates. (C) 2022 Author(s).