Abstract: We propose to measure the lifetime of short-lived excited states in highly charged ions by pump-probe experiments. Utilizing two synchronized and delayed Femtosecond pulses allows accessing these lifetimes with Femtosecond precision. Such measurements could provide sensitive tests of state-of-the art atomic structure calculations beyond the capabilities of established methods.
Abstract: calculations of QED radiative corrections to the 2P1/2 - 2P3/2 fine-structure transition energy are performed for selected F-like ions. These calculations are nonperturbative in αZ and include all first-order and many-electron second-order effects in α. When compared to approximate QED computations, a notable discrepancy is found especially for F-like uranium for which the predicted self-energy contributions even differ in sign. Moreover, all deviations between theory and experiment for the 2P1/2 - 2P3/2 fine-structure energies of F-like ions, reported recently by Li et al., Phys. Rev. A 98, 020502(R) (2018), are resolved if their highly accurate, non-QED fine-structure values are combined with the QED corrections ab initially evaluated here.
Abstract: Large-scale relativistic calculations are performed for the transition energy and line strength of the 1s22s2p 1P1− 1s22s2 1S0 transition in Be-like carbon. Based on the multiconfiguration Dirac-Hartree-Fock~(MCDHF) approach, different correlation models are developed to account for all major electron-electron correlation contributions. These correlation models are tested with various sets of the initial and the final state wave functions. The uncertainty of the predicted line strength due to missing correlation effects is estimated from the differences between the results obtained with those models. The finite nuclear mass effect is accurately calculated taking into account the energy, wave functions as well as operator contributions. As a result, a reliable theoretical benchmark of the E1 line strength is provided to support high precision lifetime measurement of the 1s22s2p 1P1 state in Be-like carbon.
Friedrich-Schiller-Universität Jena, Physikalisch-Astronomische Fakultät (2019)
Abstract: Recent advances in measurements/observations have made it possible to test small and minute fundamental physical eff ects for transition rates and line strengths in many-electron atomic systems with unprecedented accuracies. This thesis provides high-precision calculations of line strengths and lifetimes for diff erent atomic systems where we accurately account for various higher-order eff ects. In all these systems, systematically enlarged multiconfi guration Dirac-Hartree-Fock (MCDHF) wave functions are employed for calculation of the atomic states involved in the transitions to account for the relativistic correlation corrections.
Firstly, the QED sensitive magnetic dipole (M1) line strengths between the fi ne-structure levels of the ground confi gurations in B-, F-, Al- and Cl-like ions are calculated for the four elements argon, iron, molybdenum and tungsten. For these transitions, in addition to relativistic correlation corrections, the QED corrections are evaluated to all orders in αZ utilizing an eff ective potential approach. As a result, our calculations have reached an accuracy of 10−4 for the M1 line strengths. These accurate theoretical predictions provide the prerequisite for a test of QED by lifetime measurements at diff erent frequencies and timescales. This will help to find a reason for the present discrepancies between theory and experiment for B-like Ar and Al-like Fe.
Secondly, the line strength of the 1s 2 2s2p 1 P 1 – 1s 2 2s 2 1 S 0 spin allowed E1 transition in Be-like carbon is calculated. For this highly correlated transition, different correlation models are developed to account for all major electron-electron correlation contributions. The fi nite nuclear mass eff ect is accurately calculated taking into account the energy, wave functions as well as operator contributions. As a result, a reliable theoretical benchmark of E1 line strength with a relative accuracy of 1.5×10−4 is provided to support high precision lifetime measurement at GSI Darmstadt for the 1s 2 2s2p 1 P 1 state in Be-like carbon.
Finally, large-scale calculations are performed for all allowed (E1) and forbidden (M1, E2, M2) transitions among the fi ne structure levels of the 3s 2 3p 5 , 3s3p 6 and 3s 2 3p 4 3d confi gurations for Ni XII. Here, we validate all recently identifi ed tentative experimental lines with one exception. Moreover, we present ab initio lifetimes that are better than previously reported ab initio and semi-empirical values as compared to available experimental data. Thus, we provide reliable predictions in the prospects of future experiments.
Abstract: The magnetic dipole (M1) line strength between the fine-structure levels of the ground configurations in B-, F-, Al-, and Cl-like ions are calculated for the four elements argon, iron, molybdenum, and tungsten. Systematically enlarged multiconfiguration Dirac-Hartree-Fock (MCDHF) wave functions are employed to account for the interelectronic interaction with the Breit interaction included in first-order perturbation theory. The QED corrections are evaluated to all orders in αZ utilizing an effective potential approach. The calculated line strengths are compared with the results of other theories. The M1 transition rates are reported using accurate energies from the literature. Moreover, the lifetimes in the range of millisecond to picosecond are predicted including the contributions from the transition rate due to the E2 transition channel. The discrepancies of the predicted rates from those available from the literature are discussed and a benchmark data set of theoretical lifetimes is provided to support future experiments.